In the first episode of Extreme Frontiers, Charley and his team go ice hunting in Newfoundland, Lobster fishing and fresh water diving in Tobermory.

Charley hooks up with the Mounties in on a training mission, before kicking back to enjoy the Canada Day celebrations. Finally he endures a rough ride when he takes part in a rodeo in Saskatchewan.

Charley's task takes him to the peak of his fears. Armed with just a rope and a guide, Charley attempts to climb to the top of Mount Fable.

The concluding chapter of Charley's Canadian campaign sees him head for the Pacific coast. Taking to the skies, Charley pilots a small plane to Dawson City, in the heart of the Yukon. There he visits a goldmine that has been in operation since the days of the gold rush. He learns the art of strip mining and has a go at finding his fortune.